Electrocyclic reactions

The meaning of disrotation

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For thermal electrocyclic reactions involving six pi electrons, it is disrotatory motion (terminal groups rotating in opposite directions), which is observed. However, the fundamental reason is the same: the phase of the terminal lobes of the HOMO specify a required sense of rotation for bonding overlap.

Richard Windsor - Undergraduate Final Year Project 2008

Other pages of interest to do with Animated Molecular Orbitals are

Introductory | Pericyclic Reactions and Heck Catalytic Cycle