• Borohydride reduction
• Cyanide addition
• Hemiacetal formation
• Grignard and organolithium addition

• Ester hydrolysis/formation - acid catalysis
• Amide formation from acid chloride

• Acetal formation
• Cyclic acetal formation
• Enamine formation
• Wittig reaction
• Imine formation

• Configuration
• Chirality R and S
• Chiral or achiral
• Diastereoisomers
• Conformations
• Newman Projections
• Tartaric acid and Newman Projections
• Cyclohexane conformations
• Decalin conformations

• Simple S_N2 reaction
• S_N1 and S_N2
• Carbocation structure and stability

• E2 bimolecular examples
  - E2 to form diene
  - E2 Stereoselective for E
  - E2 Stereospecific Acyclic
  - E2 Cyclohexyl Diast A
  - E2 Cyclohexyl Diast B
• E1 unimolecular
• E1cb unimolecular conjugate base

• Ethylene and Bromine
• Stereospecific addition
• Epoxidation peracid
• Unsymmetrical alkenes HBr
• Regioselective addition
• Diene bromination
• Stereoisomers

• Nitration of benzene
• Friedel-Crafts alkylation
• Friedel-Crafts acylation
• Sulfonation of benzene

• Cyclopentanone Aldol - acid cat.
• Intramolecular aldol reactions
• Knoevenagel condensation
• Lithium enolates
• Mannich reaction
• Enolate acylation - Claisen condensation

• How conjugation changes the reactivity of carbonyl groups
• Enolisation
• Direct conjugate addition with enols
• Conjugate addition of enolates
• Robinson annelation
• Dimedone synthesis
• Conjugate Peroxide addition -Epoxidation

• Pyridine - Structure
  - Nucleophilic Substitution
  - Acts as a Nucleophilic Catalyst
• Pyridine N-Oxide - Structure
  - Nucleophilic Substitution
  - Cleavage of N-oxide bond
• Hydroxy Pyridine - Tautomerism
• Pyrrole - Structure
  - The Vilsmeier Reaction
  - The Mannich Reaction

• Endo v Exo
• Diels Alder: orbital explanation for the endo rule
• Regioselectivity in Diels-Alder
• Dienophile stereochemistry
• Diene stereochemistry

• Cycloadditions
  - Ozonolysis 1,3-dipolar
  - Nitrone 1,3-dipolar
• Sigmatropic rearrangements
  - [3,3]-Claisen rearrangement acyclic
  - [3,3]-Ireland-Claisen
  - [2.3]-shift sulfoxide
  - [1,5]-H shift cyclopentadiene
  - [3,3]-Fischer Indole
• Electrocyclic reactions
  - Stereospecificity
  - Conrotatory - cyclobutene
  - Disrotatory - hexatriene

• Benzilic acid
• Neighbouring group migration
• Pinacol
• Semipinacol rearrangements of diazonium salts
• Ring expansion
• Wagner-Meerwein rearrangements
• Payne rearrangement
• Beckmann rearrangement
• Favorskii rearrangement
• Rearrangement using different nucleophiles
• Stereochemistry can indicate NGP
• Which group migrates?
• Baeyer-Villiger
• Neighbouring group participation

• Bond polarization
• Ring expansion
• Beckmann fragmentation
• Fragmentations are controlled by stereochemistry
• Fragmentation of diastereoisomers
• Juvenile hormone synthesis

• Photolysis of diazomethane to produce a carbene
• Methylation of carboxylic acid using diazomethane
• Formation of carbenes
• Reactions of carbenes

• Baldwin's rules - Classes of cyclization
• Baldwin's rules - Endo-trig reactions

• Hydroboration of alkenes
• Crotyl boranes react stereospecifically with aldehydes
• Vinyl silanes react with electrophiles
• The Peterson reaction
• Stereospecific Peterson olefination

• Kosugi-Migita-Stille Coupling Reaction with optional Transition States
• Carbonylative Kosugi-Migita-Stille Coupling Reaction with optional Transition States
• Mizoroki-Heck Reaction with optional Transition States
• Carbonylation Of A Vinyl Bromide with optional Transition States
• Palladium-catalysed nucleophilic allylic substitution
• The Suzuki Reaction